The mid-infrared OPCPA-based laser facilities have recently reached the critical power for self-focusing in air . This ensures the demonstration of the major difference between the mid- and near-infrared filamentation in air: the odd optical harmonics, harshly suppressed by the material dispersion and phase-mismatch in the near-infrared (800 nm), gain reliable energies in the mid-infrared (3.9 µm) filament [1,2].
Another issue that makes mid-infrared filamentation different from the near-infrared one is a lot of molecular vibrational lines belonging to atmospheric constituents and located in the mid-infrared range . As the result the mid-infrared region of interest becomes subdivided into the bands of normal and anomalous dispersion, the former of which leads to the pulse splitting in temporal domain, while the latter produces the confined light bullet.
We simulate the 3.9-µm filamentation using Forward Maxwell equation. We include the tunnel ionization and transient photocurrent as the collapse arresting mechanism, which balances dynamically the instantaneous third-order medium response (similarly to 800-nm filamentation). The key feature that allows us to quantify the losses due to absorption bands is the accurate account of the complex linear absorption index. The absorption index obtained from Mathar model  is interpolated to the fine frequency grid (step of about 0.1 THz), and the refractive index is matched according to Kramers-Krönig relations .
If the initial Gaussian pulse has a center wavelength of 3.9 µm and a duration of 80 fs FWHM, the energy loss in the carbon dioxide (CO_2) absorption band at 4.3 µm is about 1% in the linear propagation regime. But when we take the 80-mJ pulse (about 3 critical powers for self-focusing), the Kerr-induced spectral broadening develops significantly before the clamping level of intensity is reached. In the collimated beam geometry about 2% of the initial pulse energy is absorbed on the CO_2 band before the filament is formed. In the developed filament all the partial losses due to plasma, harmonic generation and absorption on vibrational lines grow up rapidly with the propagation distance, and the absorption on vibrational lines overwhelms all the rest ones. Indeed the new mechanism is revealed – the linear absorption is enhanced by the nonlinear spectral broadening. Thus, the nonlinearly enhanced linear absorption (NELA) is formed. The rotational transitions are estimated to consume as much energy as the free electron generation mechanism , which is less than NELA for 3.9-µm filament.
In conclusion, in the 3.9-µm filament the excitations of molecular absorption lines are estimated to provide the major optical losses in the atmosphere as compared with plasma and high-frequency conversion.
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 P. Panagiotopoulos et al., Nat. Photonics 9, 543 (2015).
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 N. A. Panov et al., Phys. Rev. A 94, 041801 (2016).
 S. Zahedpour et al., Phys. Rev. Lett. 112, 143601 (2014).
Daniil Shipilo, Nicolay Panov, Vera Andreeva, Olga G. Kosareva, Alexander M. Saletski, Huai-Liang Xu, and Pavel Polynkin, "Nonlinearly enhanced linear absorption under filamentation in mid-infrared (Conference Presentation)," Proc. SPIE 10228, Nonlinear Optics and Applications X, 1022807 (Presented at SPIE Optics + Optoelectronics: April 24, 2017; Published: 8 June 2017); https://doi.org/10.1117/12.2264456.5463398257001.
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