From Event: SPIE Organic Photonics + Electronics, 2017
To date, the most widely employed technique to investigate the crystal structure and morphology of perovskite films have been SEM and X-ray diffraction. Most perovskite films are highly polycrystalline and thus traditional imaging techniques cannot easily isolate single crystallites or determine the statistics of lateral grain size or crystal size and morphology. A further limitation is that both SEM and other scanning probe microscopy techniques are surface-sensitive, with the bulk of the material being largely inaccessible using conventional imaging methods.
To gain better insight into a perovskite film, we scan an X-ray beam focused to 400 nm across a sample, while simultaneously recording wide-angle X-ray scattering patterns. Such scanning nanofocus x-ray diffraction (nXRD) techniques have been employed to resolve local variations in structure across a broad range of materials and research fields, however this is the first time they have been applied to a perovskite film.
We describe a method to in which each scattering pattern is analysed, allowing a classification to be made of individual perovskite grains according to a specific Miller plane. Using this method, we show that nXRD is able to resolve the extent of individual perovskite grains buried within a polycrystalline film (grain segmentation). We then use nXRD and SEM to demonstrate that the perovskite film coverage can be controlled by varying the temperature of the substrate during spin-coating. We conclude by showing that solar cells with a perovskite layer cast on a substrate held at a relatively high temperature result in devices with higher PCE.
David G. Lidzey, "Mapping structural properties of lead halide perovskites by scanning nanofocus x-ray diffraction (Conference Presentation)," Proc. SPIE 10363, Organic, Hybrid, and Perovskite Photovoltaics XVIII, 103631E (Presented at SPIE Organic Photonics + Electronics: August 10, 2017; Published: 19 September 2017); https://doi.org/10.1117/12.2275741.5581151954001.
Conference Presentations are recordings of oral presentations given at SPIE conferences and published as part of the conference proceedings. They include the speaker's narration along with a video recording of the presentation slides and animations. Many conference presentations also include full-text papers. Search and browse our growing collection of more than 12,000 conference presentations, including many plenary and keynote presentations.
Monte Carlo based light propagation models to improve efficacy of biophotonics based therapeutics of hollow organs and solid tumours including photodynamic therapy and photobiomodulation (Conference Presentation)