25 July 1979 Correlation Spectroscopy
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Proceedings Volume 0164, 4th European Electro-Optics Conf; (1979) https://doi.org/10.1117/12.965502
Event: Fourth European Electro-Optics Conference, 1978, Utrecht, Netherlands
Today, the interpretation of spectroscopic data with the aid of time-dependent autocorrelation functions (acfs) has found widespread application to molecules in solids, liquids and dense gases. In this paper the two dominant relaxation processes influencing the acts of rotational and vibrational relaxation are reviewed. The influence of Coriolis coupling on the rotational acfs of degenerate vibrations is emphasized. Experimental acfs are discussed for the rotational relaxation of HC1 in tetrachlorides, OH- and OD- ions in single crystals of alkalihalides, gaseous chloroform and of methanes in liquid argon as well as for intramolecular vibrational relaxation in the metal carbonyls Cr(CO)6, Mo(CO )6 and W(CO)6.
© (1979) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
K. Muller, K. Muller, } "Correlation Spectroscopy", Proc. SPIE 0164, 4th European Electro-Optics Conf, (25 July 1979); doi: 10.1117/12.965502; https://doi.org/10.1117/12.965502

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