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30 December 1981 Self-Focusing In SF6
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Proceedings Volume 0288, Los Alamos Conf on Optics '81; (1981)
Event: Los Alamos Conference on Optics, 1981, Los Alamos, United States
We show by explicit calculation of our previously published quasicontinuum model that the molecular susceptibility rapidly approaches zero as higher excited states of the molecule become populated. Hence the overtones of the ν3-pumped mode are totally responsible for the self tocusing effects in SF6. We explicitly calculate the ν3 ladder contribution to the susceptibility. Our vibrational model is a classical triply degenerate anharmonic oscillator in the Cartesian basis with the anharmonicity parameters chosen to be consistent with the latest spectroscopic analysis of the 3ν3 overtone spectrum. The rotational struc-ture is represented by a distribution of these oscillators where the distribution is chosen to correspond to the spectrum of the ν3 fundamental. We find good agreement with the 300K self-focusing data of Nowak and Ham at CO2 P(28), P(20) and P(10) in SF6.
© (1981) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
J. R. Ackerhalt and H. W. Galbraith "Self-Focusing In SF6", Proc. SPIE 0288, Los Alamos Conf on Optics '81, (30 December 1981);

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