Autoxidation Of Hydrazine, Monomethylhydrazine, And Unsymmetrical Dimethylhydrazine

Daniel A. Stone

doi:10.1117/12.932120

29 October 1981 Autoxidation Of Hydrazine, Monomethylhydrazine, And Unsymmetrical Dimethylhydrazine

Daniel A. Stone

Proceedings Volume 0289, 1981 Intl Conf on Fourier Transform Infrared Spectroscopy; (1981) https://doi.org/10.1117/12.932120
Event: 1981 International Conference on Fourier Transform Infrared Spectroscopy, 1981, Columbia, United States

Abstract

The autoxidation reactions of hydrazine (HZ), monomethylhydrazine (MMH), and unsymmet-trical dimethylhydrazine (UDMH) at concentrations of 1 to 30 parts-per-million (ppm) were studied under simulated atmospheric conditions by long-path Fourier transform infrared spectroscopy in a 60-liter glass chamber. The observed reaction products for HZ were water and ammonia; for MMH they were methane, methanol, water and methyldiazene; and for UDMH it was formaldehyde dimethylhydrazone. Half lives were 133 minutes for HZ, 250 minutes for MMH, and 83.5 hours for UDMH.

Citation Download Citation

Daniel A. Stone "Autoxidation Of Hydrazine, Monomethylhydrazine, And Unsymmetrical Dimethylhydrazine", Proc. SPIE 0289, 1981 Intl Conf on Fourier Transform Infrared Spectroscopy, (29 October 1981); https://doi.org/10.1117/12.932120

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available