14 June 1984 Photochemistry Of Adsorbed Organometallics: Fe(CO)5 on SiO2
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Proceedings Volume 0459, Laser-Assisted Deposition, Etching, and Doping; (1984) https://doi.org/10.1117/12.939432
Event: 1984 Los Angeles Technical Symposium, 1984, Los Angeles, United States
The photochemistry of Fe(CO)5 adsorbed on Si02 at submonolayer coverage has been studied. IR and UV-visible spectra show that the only significant product is Fe3(C0)12 rather than Fe2(C0)9, which is the product observed upon irradiation of Fe(C0)5 in the gas or liquid phase or in solution. Evidence is presented that the intermediate reacting to give Fe3(CO)12 on the Si02 surface is a species designated Fe(C0)4(Si02), which denotes a complex between Fe(C0)4 and the terminal surface hydroxyl groups or siloxane bridging oxo groups.
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Robert L. Jackson, Robert L. Jackson, "Photochemistry Of Adsorbed Organometallics: Fe(CO)5 on SiO2", Proc. SPIE 0459, Laser-Assisted Deposition, Etching, and Doping, (14 June 1984); doi: 10.1117/12.939432; https://doi.org/10.1117/12.939432


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