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The optical absorption of tetrahedrical anions such as phosphates and sulfates has been studied in fluorozirconate glasses. A ternary fluoride glass in the system ZrF4-BaF2-LaF3, was doped with calculated amounts of KHSO4 or NaPO3. A significant reduction of the OH-absorption has been achieved using a low temperature fluorination treatment and a high temperature refining under a very dry atmosphere. A minimum transmission loss of 58 dB/km at 2.9 μm was observed on a fiber 60 meters in length. Increasing heating time or temperature for the refining stage however results in higher scattering losses.
Marcel Poulain,Mohammed Saad,Gwenael Maze, andVincent Cardin
"Analysis Of Optical Losses In Fluoride Glass Fibers.", Proc. SPIE 0505, Advances in Optical Materials, (26 December 1984); https://doi.org/10.1117/12.964641
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Marcel Poulain, Mohammed Saad, Gwenael Maze, Vincent Cardin, "Analysis Of Optical Losses In Fluoride Glass Fibers.," Proc. SPIE 0505, Advances in Optical Materials, (26 December 1984); https://doi.org/10.1117/12.964641