4 February 1988 Conjugated Polymers For Nonlinear Optics
Author Affiliations +
The large nonresonant third order optical nonlinearities and fast response times of conjugated polymers make them attractive materials for nonlinear optics. The X(3) spectrum of polyacetylene and polydiacetylenes show similar structure, with magnitudes that agree with calculations of X(3) for the infinite polyene, as well as from the extrapolation of the calculated hyperpolarizabilities of finite polyenes. Of the conjugated polymers, the polydiacetylenes offer the best combination of physical properties since they can be obtained as large single crystals, thin crystalline films, Langmuir-Blodgett multilayers or as spun thin films. Unfortunately, all the conjugated polymers show some sensitivity to oxygen, though single crystals of polydiacetylenes are robust.
© (1988) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Gregory L. Baker, Gregory L. Baker, S. Etemad, S. Etemad, F. K ajzar, F. K ajzar, } "Conjugated Polymers For Nonlinear Optics", Proc. SPIE 0824, Advances in Nonlinear Polymers and Inorganic Crystals, Liquid Crystals and Laser Media, (4 February 1988); doi: 10.1117/12.941967; https://doi.org/10.1117/12.941967


New Polydiacetylenes Incorporating Mesogenic Side-Chains
Proceedings of SPIE (February 04 1988)
Polymer Systems For Nonlinear Optical Devices
Proceedings of SPIE (September 25 1989)
Fast Nematic Liquid Crystal Spatial Light Modulator
Proceedings of SPIE (February 04 1988)
A Unified Theory For The WORM Sensitivity Function
Proceedings of SPIE (February 04 1988)
Optical Bistability In Dimer-Monomer Dye Systems
Proceedings of SPIE (February 04 1988)

Back to Top