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Nitramine ligands have very rarely been employed in metal complex chemistry. This paper describes several new metal-nitraminato compounds of Cu(II), Ni(II) and Pd(II) and their crystal structures. Some of the compounds are potentially interesting as nitramine burn-rate catalysts. To this end, gas product speciation studies were conducted on the compounds under conditions of high heating rate thermolysis. Selected results are described.
Stephen F Palopoli andThomas B Brill
"Synthesis And Thermolysis Of Metal Complexes Containing Energetic Ligands", Proc. SPIE 0872, Propulsion, (9 May 1988); https://doi.org/10.1117/12.943744
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Stephen F Palopoli, Thomas B Brill, "Synthesis And Thermolysis Of Metal Complexes Containing Energetic Ligands," Proc. SPIE 0872, Propulsion, (9 May 1988); https://doi.org/10.1117/12.943744