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used hydroxylamine nitrate decomposes within a few minutes in the temperature range 130-140°C. Added ammonium ion is converted to N2, while hydrazinium ion is converted to HN3. Nitrous acid is an intermediate and its formation is rate-determining. A hygride transfer process is postulated. The reaction pathways have been elucidated by use of N tracers.
Jimmie C Oxley andKay R Brower
"Thermal Decomposition Of Hydroxylamine Nitrate", Proc. SPIE 0872, Propulsion, (9 May 1988); https://doi.org/10.1117/12.943754
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Jimmie C Oxley, Kay R Brower, "Thermal Decomposition Of Hydroxylamine Nitrate," Proc. SPIE 0872, Propulsion, (9 May 1988); https://doi.org/10.1117/12.943754