Samples of a martensitic stainless steel containing 0.47%C and 12.8%Cr were surface melted using continuous wave CO2 laser radiation and a multiple pass technique. The structure of the laser modified layer was studied by optical microscopy, scanning electron microscopy and X ray diffraction. The melted zone presents a narrow region near the fusion line with a ferritic--martensitic structure, that seems to have solidified by an almost partitionless mechanism. It is followed by a cellular-dendritic structure in the center of the melted trail, that consists on δ -ferrite, martensite and M23C6 carbide. The absence of austenite is surprising; it can be explained by the tempering effects of the solidification structure, due to subsequent laser passes.
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