28 February 2017 Crystal structure and optical properties of a neodymium trifluoroacetate complex for liquid laser
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Proceedings Volume 10256, Second International Conference on Photonics and Optical Engineering; 102564Z (2017) https://doi.org/10.1117/12.2260699
Event: Second International Conference on Photonics and Optical Engineering, 2016, Xi'an, China
Abstract
The neodymium trifluoroacetate complex was synthesized and characterized by single-crystal X-ray diffraction, elemental and TG analysis, FT-IR spectra, and PL spectra. The optical properties of the liquid medium were studied. From the absorption and luminescence spectra, the Judd-Ofelt parameters of the Nd(CF3COO)3 dissovled in phosphorus oxychloride were obtained. Based on the crystal structure, the effects of crystal field and bond valance properties on three intensity parameters Ωt(t=2,4,6) and emission cross-section were analyzed in detail. The emission cross-section of 4F3/24I11/2 fluorescence transition (3.63×10-20cm2) of the new neodymium compound was higher than those of other Nd(III) complexes and even comparable with some laser glasses
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Jiangbo She, Jiangbo She, Rongzhi Nie, Rongzhi Nie, Xin Sun, Xin Sun, Bo Peng, Bo Peng, } "Crystal structure and optical properties of a neodymium trifluoroacetate complex for liquid laser", Proc. SPIE 10256, Second International Conference on Photonics and Optical Engineering, 102564Z (28 February 2017); doi: 10.1117/12.2260699; https://doi.org/10.1117/12.2260699
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