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In this paper antimony-germanate oxide glasses doped with Er3+ and co-doped with Er3+/Ag ions were synthesized and measured in terms of absorbance and near-infrared emission parameters. Series of glasses with different molar concentration of erbium oxide led to the optimal rare earth ion content equal to 0.8 mol% Er2O3. The effect of the incorporation silver ions to the glass matrix on the absorption spectrum in the UV range (Ag: S0 → S1, 350 nm) was confirmed formation of silver ions as a nanoparticles or nanoclusters. In samples co-doped with Er3+/Ag ions decrease of near-infrared luminescence intensity has been observed indicating predominant energy transfer from erbium to silver ions (Er3+ → Ag).
Tomasz Ragin,Jacek Zmojda,Marcin Kochanowicz,Piotr Miluski,Renata Jadach,Maciej Sitarz,Dominik Dorosz, andJan Dorosz
"Spectroscopic properties and energy transfer in Er/Ag co-doped antimony oxide glass", Proc. SPIE 10445, Photonics Applications in Astronomy, Communications, Industry, and High Energy Physics Experiments 2017, 104454V (7 August 2017); https://doi.org/10.1117/12.2280278
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Tomasz Ragin, Jacek Zmojda, Marcin Kochanowicz, Piotr Miluski, Renata Jadach, Maciej Sitarz, Dominik Dorosz, Jan Dorosz, "Spectroscopic properties and energy transfer in Er/Ag co-doped antimony oxide glass," Proc. SPIE 10445, Photonics Applications in Astronomy, Communications, Industry, and High Energy Physics Experiments 2017, 104454V (7 August 2017); https://doi.org/10.1117/12.2280278