21 November 2017 Optical characterization of infrared telluride glass fibers for space use
Author Affiliations +
Proceedings Volume 10566, International Conference on Space Optics — ICSO 2008; 105660X (2017) https://doi.org/10.1117/12.2308263
Event: International Conference on Space Optics 2008, 2008, Toulouse, France
Abstract
High Tellurium (Te) content chalcogenide glass fibers are considered as candidates for single mode waveguides in the upper wavelength range (10 – 20 μm) of the DARWIN mission. In this paper two methods for IR optical characterization of the Te glass fibers are presented, including (1) a broadband spectral technique using an FTIR spectrophotometer and (2) a CO2 laser set-up for measuring the fiber attenuation at 10.6 μm. In both methods the optical attenuation (in dB/m) of experimental mono index Te glass fibers of around 500 μm diameter has been determined by applying the fiber cut-back technique. Some typical results of both methods for a few different types of high Te-glass fibers will be shown. Since Te-glasses are semiconducting materials, the optical properties of Te-glass fibers strongly depend on temperature. Preliminary low temperature measuring results confirm the beneficial effect of cooling on the transmission of high Te glass fibers.
Faber, Cheng, Gielesen, Boussard-Plédel, Maurugeon, Bureau, Zhang, Lucas, and Do Carmo: OPTICAL CHARACTERIZATION OF INFRARED TELLURIDE GLASS FIBERS FOR SPACE USE

1.

INTRODUCTION

An important measuring technique under study for the DARWIN planet finding mission, is nulling interferometry [1,2]. The main goal of this mission is to identify terrestrial planets, orbiting around nearby stars and capable of having an atmosphere, so possibly supporting life. The principle of nulling interferometry is the destructive interference of the intense light emitted by a central star, thus enabling the detection of the weak infrared emission lines of the orbiting planet. This technique requires a perfect wavefront of the light beams to be combined in the interferometer. By using a single mode waveguide before detection, higher order modes are filtered and a virtually perfect plane wavefront is obtained

Since the main emission lines of the relevant atmospherical components like CO2, O3 and water vapour are all in the mid IR, from 4 – 20 μm, the envisaged single mode waveguides must be transparent in this spectral range.

Step index, Te-As-Se (TAS) chalcogenide glass fibers are considered to be suitable waveguides for the lower DARWIN wavelength range from 4 – 10 μm [1,2]. In this paper, high Te content chalcogenide glasses are proposed as candidates for waveguides in the upper (10 – 20 μm) DARWIN wavelength range. Typical results of optical characterization on unclad, mono-index fibers of high Te glass compositions are presented and discussed here.

2.

EXPERIMENTAL

2.1

Preparation of unclad high Te glass fibers

Unclad (mono index) high Te content fibers were manufactured from the following chemical glass compositions:

  • TeGeGaI

  • TeGeI

  • TeGeSe

Using special raw materials preparation, chemical purification and glass melting procedures [3], glass rods of about 9 mm diameter and about 10 cm length were manufactured. These glass rods were drawn to mono index fibers (ø from 400 – 550 μm), using a special fiber drawing machine, described previously [4]. Several meters of three TeGeGaI type mono-index fibers (two non-purified ø400 μm and one purified ø400 μm/ø52O μm) were drawn, showing a good surface quality, free of defects or crystallization (see Fig. 1.).

Fig. 1.

Mono-index TeGeGaI fiber on drum

00024_PSISDG10566_105660X_page_2_1.jpg

Similar preparation procedures were used to manufacture fibers of more than 10 meters length from the TeGeI and TeGeSe glass compositions.

2.2

Infrared optical characterization methods

(1)

Broadband spectral set-up

An experimental set-up was built for measuring the spectral loss of the unclad (mono-index) Te glass fibers in the region 4 – 20 μm by the fiber cut-back technique. The components of this set-up are described in Table 1.

Table 1

Components of broadband spectral set-up

ComponentSpecification
Light sourceCeramic coil, emitting from 1.5 – 55 μm
DetectorMIRTGS (1 – 45 μm) with Csl window
Detection instrumentPerkin Elmer 2000 FTIR spectrophotometer with Csl beamsplitter and Csl window
Fiber holderAluminium substrate with V-groove on alignment stage
OpticsMirrors for focussing the light into the fiber
Pinhole0.9 mm diameter for defining the focus point at the input of the fiber

Some pictures of the set-up are presented in Fig. 2.

Fig. 2.

Top view of broadband spectral set-up (top) with details, showing the fiber (on Al substrate) in front of the pinhole (bottom left) and the output of the fiber close to the detector window (bottom right)

00024_PSISDG10566_105660X_page_3_1.jpg

(2)

CO2 laser set-up

The attenuation measurements at 10.6 μm using the cut-back method are performed with a pulsed CO2 laser (SYNRAD J48-1SW). The maximum output power is 10W, the beam size is about 3 mm and the pulse frequency is 5 kHz. The output optical power can be tuned by changing the duty cycle. The set-up is sketched in Fig. 3.

Fig. 3.

Pulsed CO2 laser set-up for fiber attenuation measurements at 10.6 μm

00024_PSISDG10566_105660X_page_3_2.jpg

3.

RESULTS OF OPTICAL ATTENUATION MEASUREMENTS ON TE-GLASS FIBERS

3.1

Attenuation at room temperature

Spectral attenuation of TeGeGal fibers

The transmission of two TeGeGal fiber samples, approximately 5 cm long, was measured using the broadband spectral set-up. One fiber sample was prepared from an untreated glass and another sample from a similar glass composition, after an additional chemical purification procedure to remove (oxygen) impurities.

The corresponding spectra are presented in Fig. 4.

Fig. 4.

Comparison of spectral transmission of a 5 cm fiber of purified and non-purified (untreated) TeGeGaI mono-index fiber

00024_PSISDG10566_105660X_page_3_3.jpg

It can be seen in Fig. 4 that the TeGeGaI fiber has the highest transmission in the 12 – 13 μm region. Besides, part of the absorption of the TeGeGaI fiber in the region 15 – 20 μm is extrinsic, probably due to oxygen related impurities. By the application of proper purification methods, the transmission in the region 15 – 20 μm can be increased.

Next, the spectral attenuation of a 9 cm long sample of the purified TeGeGaI fiber was determined by cutting back this fiber piece in 3 steps to about 3 cm.

The measured average spectral attenuation is presented in Fig. 5.

Fig. 5.

Averaged spectral attenuation (dB/cm) of a purified TeGeGaI fiber at room temperature determined by fiber cut-back method

00024_PSISDG10566_105660X_page_4_1.jpg

A minimum in the attenuation of 0.4 dB/cm was found between 12 and 13 μm. The attenuation between 16 and 20 μm increases from a value around 1.5 dB/cm to 3 dB/cm.

Although the measured values for the spectral loss are still relatively high, these results prove that the purified TeGeGaI fiber transmits light in the region between 15 and 20 μm through short fiber samples. This performance can probably be improved by advanced glass manufacturing processing and improved purification methods.

Attenuation of high Te fibers at 10.6 μm

The attenuation at 10.6 μm of fiber samples of about 50 cm long of the glass types TeGeGaI, TeGeI and TeGeSe was determined by cutting back these fibers in many steps to about 10 cm. After each cut the transmitted light intensity through the remaining fiber length was measured.

The results of the fiber cut-back measurements with the CO2 laser set-up are summarized in Table 2.

Table 2

Attenuation at 10.6 μm of different high Te-glass fiber types (unclad), made from purified glasses

Fiber typeAttenuation (dB/cm)
TeGeGaI0.46
TeGeI0.17
TeGeSe0.10

The measured loss value at 10.6 μm of 0.46 dB/cm for the TeGeGaI glass fiber corresponds reasonably well with the measured values between 10 and 11 μm in Fig. 5. Apparently, the optical loss at the CO2 laser wavelength (10.6 μm) of the glass fiber types TeGeI and particularly TeGeSe is considerably lower.

This observation was confirmed by other spectral measurements, not reported here, which showed that the TeGeSe glass fibers have a minimum attenuation between 10 and 11 μm, so slightly shifted to shorter wavelengths compared to TeGeGaI fibers. The origin of the differences in the optical loss between the different fiber types (intrinsic/extrinsic absorptions, glass quality, crystals in the fiber, etc.) is still under study.

3.2

Attenuation at low temperatures

In order to simulate temperature conditions in space, a qualitative experiment was carried out on a 135 mm long TeGeGaI-fiber, cooled by liquid N2, using the broadband FTIR set-up of Fig. 2.. The spectrum measured at low temperature was compared to the spectrum of the same fiber at room temperature and the ratio of both curves was calculated, as shown in Fig. 6.

Fig. 6.

Factor of improvement in transmission of a TeGeGaI fiber at liquid nitrogen compared to room temperature

00024_PSISDG10566_105660X_page_4_2.jpg

It can be seen in Fig. 6 that the transmission of the TeGeGaI fiber increases at low temperature and that the improvement due to cooling is wavelength dependent. The minimum improvement in optical transmission at liquid N2 temperature is a factor of 2 at about 13 μm.

4.

CONCLUDING REMARKS

The optical loss of different types of high Te content, unclad glass fibers was measured by the fiber cut-back method, using a broadband FTIR set-up and a single wavelength CO2 laser set-up. Optical attenuation values down to 0.1 – 0.5 dB/cm were measured, depending on glass type, glass preparation/purification processes and IR wavelength. The TeGeSe glass fiber samples appeared to have the lowest loss of 0.1 dB/cm at 10.6 μm.

Since high Te-glasses are semiconducting materials, the optical properties of Te-glass fibers strongly depend on temperature. Preliminary low temperature measurements showed an improvement of the Te glass fiber transmission at liquid nitrogen temperatures of minimum a factor 2.

Taking into account the optical transmission results, it is concluded that high Te-glass fibers are realistic candidates for satisfying the DARWIN waveguide requirements in the upper wavelength range from 10 –20 μm.

5.

5.

REFERENCES

1. 

A.J. Faber, L.K. Cheng, W.L.M. Gielesen,C. Boussard-Pledel, P. Houizot, S. Danto, J. Lucas and J. Pereira Do Carmo, “Single-mode chalcogenide glass fiber as wavefront filter for the DARWIN planet finding mission”, Proc. 6th Int. Conf. on Space Optics, ESTEC, Noordwijk, The Netherlands, 27 - 30 June 2006Google Scholar

2. 

P. Houizot, C. Boussard-Plédel, A.J. Faber, L.K. Cheng, B. Bruno, P.A. Van Nijnatten, W.L.M. Gielesen, J. Pereira do Carmo, J. Lucas, “Infrared single mode chalcogenide glass fiber for space”, OPTICS EXPRESS, Vol. 15, No. 19, (17 September 2007)Google Scholar

3. 

A. Wilhelm, C. Boussard-Plédel, Q. Coulombier, J. Lucas, B. Bureau, P. Lucas, ‘Development of far-infrared-transmitting Te based glasses suitable for carbon dioxide detection and space optics’, Advanced Materials, 19, (2007), 3796–3800Google Scholar

4. 

S. Hocdé, C. Boussard-Plédel, G. Fonteneau, J. Lucas, ‘Chalcogen based glasses for IR fiber chemical sensors’, Solid State Sciences, 3 (3), (2001), 279Google Scholar

© (2017) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
A.J. Faber, A.J. Faber, L.K. Cheng, L.K. Cheng, W. L.M. Gielesen, W. L.M. Gielesen, C. Boussard-Plédel, C. Boussard-Plédel, S. Maurugeon, S. Maurugeon, B. Bureau, B. Bureau, X.H. Zhang, X.H. Zhang, J. Lucas, J. Lucas, J. Pereira do Carmo, J. Pereira do Carmo, } "Optical characterization of infrared telluride glass fibers for space use", Proc. SPIE 10566, International Conference on Space Optics — ICSO 2008, 105660X (21 November 2017); doi: 10.1117/12.2308263; https://doi.org/10.1117/12.2308263
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