Presentation + Paper
14 September 2018 Photo-stimuli responsive supramolecular materials using supramolecular machine
Yoshinori Takashima, Akira Harada
Author Affiliations +
Abstract
Molecular recognition is essential for realizing functional supramolecular materials. Non-covalent host-guest interactions are an effective tool to introduce switching and functional properties into materials. This paper focuses on the photo responsive supramolecular actuators. These functions have been achieved by reversible bond formation with cyclodextrins (CDs). To prepare a supramolecular actuator using host-guest complexes, two approaches have been introduced. The first is the functionalization of a supramolecular gel actuator by changing the cross-linking density, and the second is the functionalization of a topological gel actuator by changing length of the cross-linking points. Both actuators exhibit contractive bending behavior. This paper summarizes advancements in supramolecular materials that function through the chemical mechanism of host-guest interactions and the physical mechanism of the sliding motion of ring molecules.
Conference Presentation
© (2018) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Yoshinori Takashima and Akira Harada "Photo-stimuli responsive supramolecular materials using supramolecular machine", Proc. SPIE 10740, Molecular Machines, 107400C (14 September 2018); https://doi.org/10.1117/12.2322130
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KEYWORDS
Actuators

Polymers

Molecules

Ultraviolet radiation

Cadmium sulfide

Molecular machines

Polymeric actuators

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