In this article, we studied new porous material, which is based on artificial opals, made of 300-nm-diameter nanoporous SiO2 globules and annealed at different temperatures in the range of 200–1500◦C, as a prospective terahertz (THz) optical material. It was demonstrated experimentally that the THz optical properties of such material can be varied in a wide range (e.g. its refractive index varies from 1.65 to 1.95) by annealing, being a function of the total material porosity. Additionally, this material has rather low THz absorption coefficient (by field), which decreases from 10 to 1 cm−1 with increasing annealing temperature. Based on the Bruggeman effective medium theory, the practical model was introduced to predict the optical properties of the considered material as a function of the annealing temperature. A wide tunability of refractive index and a low-to-moderate THz-wave absorption, make the discussed nanoporous SiO2 a promising THz optical material.
|