Multi-timescale dynamics in glasses: optical dephasing and solute-solvent interactions

L. Ravi Narasimhan; Dee William Pack; Andreas Elschner; Yu Sheng Bai; Michael D. Fayer

doi:10.1117/12.17889

1 April 1990 Multi-timescale dynamics in glasses: optical dephasing and solute-solvent interactions

L. Ravi Narasimhan, Dee William Pack, Andreas Elschner, Yu Sheng Bai, Michael D. Fayer

Author Affiliations +

Proceedings Volume 1209, Picosecond and Femtosecond Spectroscopy from Laboratory to Real World; (1990) https://doi.org/10.1117/12.17889
Event: OE/LASE '90, 1990, Los Angeles, CA, United States

Abstract

Picosecond photon echo (PE) experiments are used to examine the optical dephasing and intermolecular interactions of organic chromophores in a variety of glassy organic and polymer hosts. The inherent disorder in these systems leads to dynamics which span times from picoseconds to hours and longer. The temperature dependent optical dephasing as measured by the PE follows a power law characteristic of tunnelling twolevel systems (TLS) at low temperatures (1 °K to 4 °K) and is exponentially activated at higher temperatures due to dephasing by additional modes. The nature of these modes will be addressed. These data and those from other line narrowing experiments such as hole burning allow the study both of fast dephasing processes and spectral diffusion due to slow fluctuations in the host. The observed lineshapes and holewidths require dipolar coupling between the chromophore and TLS and offer information on the distribution of relaxation rates. Furthermore, techniques sensitive to different timescales are used to examine host dynamics by removing the guest-host coupling from consideration. The data are discussed in conjunction with recently developed theoretical treatments of dephasing in disordered systems.

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L. Ravi Narasimhan, Dee William Pack, Andreas Elschner, Yu Sheng Bai, and Michael D. Fayer "Multi-timescale dynamics in glasses: optical dephasing and solute-solvent interactions", Proc. SPIE 1209, Picosecond and Femtosecond Spectroscopy from Laboratory to Real World, (1 April 1990); https://doi.org/10.1117/12.17889

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