Ab initio calculations on electronic states of ionic rubidium fluoride excimer

Ken-ichi Ueda; Xing Da; Hiroshi Takuma

doi:10.1117/12.18481

1 June 1990 Ab initio calculations on electronic states of ionic rubidium fluoride excimer

Ken-ichi Ueda, Xing Da, Hiroshi Takuma

Proceedings Volume 1225, High-Power Gas Lasers; (1990) https://doi.org/10.1117/12.18481
Event: OE/LASE '90, 1990, Los Angeles, CA, United States

Abstract

Ab initio calculations for the electronic states of (RbF)(+) ionic excimer arising from the Rb(+) + F,Rb(2+) + F(-),Rb(+) + F(-), and Rb + F(+) separated states are reported. The emission at 130 nm is identified to the transition between the ionic 2 2 Sigma(+) and l 2 Sigma(+) states which was estimated to occur at 124 nm with an spontaneous lifetime of 0.9 ns. The ionic 2 2 Pi state is found to lie close to the ionic 2 2 Sigma(+) state of a lifetime of 5.6 ns.

Citation Download Citation

Ken-ichi Ueda, Xing Da, and Hiroshi Takuma "Ab initio calculations on electronic states of ionic rubidium fluoride excimer", Proc. SPIE 1225, High-Power Gas Lasers, (1 June 1990); https://doi.org/10.1117/12.18481

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