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So-called split Ga vacancies, where a next-nearest-neighbor Ga atom relaxes strongly creating a structure with two "half-Ga vacancies" are the main defect observed with positron annihilation in almost all as-grown β-Ga2O3, irrespective of doping or conduction type. Unrelaxed Ga vacancies are observed in some samples subjected to high-energy particle irradiation. It also appears to n-type doping with Si promotes the formation of unrelaxed Ga vacancies. In spite of the high concentrations of the Ga vacancy related defects in the as-grown materials, the electrical compensation appears not to be directly affected by the vacancies.
Conference Presentation
(2024) Published by SPIE. Downloading of the abstract is permitted for personal use only.
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F. Tuomisto, I. Zhelezova, I. Makkonen, "Split and unrelaxed Ga vacancies in β-Ga2O3," Proc. SPIE 12887, Oxide-based Materials and Devices XV, 1288704 (15 March 2024); https://doi.org/10.1117/12.3008560