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Auxillary optics used to measure the spectral properties of ions doped in crystal may play a dominant role in causing the shift of the peak frequency of the spectrum emitted by the ions. Therefore consideration has to be to the contribution to this spectral shift due to source correlation in addition to the shift caused by phonon scattering crystal field and tnperature effects etc.
H. C. Kandpal,K. C. Joshi, andJ. S. Vaishya
"Correlation-induced spectroscopy of rare-earth ions doped in crystals", Proc. SPIE 1319, Optics in Complex Systems, (1 July 1990); https://doi.org/10.1117/12.34821
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H. C. Kandpal, K. C. Joshi, J. S. Vaishya, "Correlation-induced spectroscopy of rare-earth ions doped in crystals," Proc. SPIE 1319, Optics in Complex Systems, (1 July 1990); https://doi.org/10.1117/12.34821