Resonance Raman study of Zn-porphyrin pi-anions

G. P. Gurinovich; Sergei G. Kruglik; Vladimir V. Kvach; S. N. Terekhov

doi:10.1117/12.57271

1 May 1991 Resonance Raman study of Zn-porphyrin pi-anions

G. P. Gurinovich, Sergei G. Kruglik, Vladimir V. Kvach, S. N. Terekhov

Proceedings Volume 1403, Laser Applications in Life Sciences; (1991) https://doi.org/10.1117/12.57271
Event: Laser Applications in Life Sciences, 1990, Moscow, Russian Federation

Abstract

The first attempts to obtain resonance Raman (RR) spectra of metalloporphyrin ir-anions1 and the works that followed24 showed that RR spectroscopy could be regarded as a method for studying the electronic structure of these compounds. This paper deals with the RR study of ir-anions of Zn-porphyrin complexes. We focus on the analysis of changes in the electronic structure, force field and ir-orders of bonds which take place in the porphyrin cycle as a result of successive single-electron reduction: from monoanion to tetraanion.

Citation Download Citation

G. P. Gurinovich, Sergei G. Kruglik, Vladimir V. Kvach, and S. N. Terekhov "Resonance Raman study of Zn-porphyrin pi-anions", Proc. SPIE 1403, Laser Applications in Life Sciences, (1 May 1991); https://doi.org/10.1117/12.57271

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