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The rate at which one atom in a photodetector is ionized by a beam of classical light is considered. A detailed examination of the probability of transition is presented, using first- order time-dependent perturbation theory and the rotating wave approximation. This method usually leads to the well-known rule called 'golden' by Fermi. The authors have made a more accurate analysis based on numerical quadrature techniques. They discover a curious oscillation in the probability for photoionization for short times and a temporal shift in the curve as compared to the results given by the golden rule. The shift is approximated analytically and found to correspond with the numerical result to a high precision. Results for the probability of photoionization are shown without using the rotating wave approximation.
Heidi Fearn andWillis E. Lamb Jr.
"Corrections to the Golden Rule", Proc. SPIE 1497, Nonlinear Optics and Materials, (1 September 1991); https://doi.org/10.1117/12.46791
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Heidi Fearn, Willis E. Lamb Jr., "Corrections to the Golden Rule," Proc. SPIE 1497, Nonlinear Optics and Materials, (1 September 1991); https://doi.org/10.1117/12.46791