1 March 1992 Determination of polymer end and functional groups by NIR spectrometry
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Proceedings Volume 1575, 8th Intl Conf on Fourier Transform Spectroscopy; (1992) https://doi.org/10.1117/12.56407
Event: Eighth International Conference on Fourier Transform Spectroscopy, 1991, Lubeck-Travemunde, Germany
Abstract
The knowledge of accurate hydroxyl and acid numbers as well as water content is of great value for process control and quality assurance in the polymer industry. Standard methods are lengthy procedures and require large quantities of chemicals. Therefore rapid and simple spectrometric determinations are preferable. Especially near-infrared spectrometry in combination with chemometric methods offers some distinct advantages for such applications. The properties of polyesters derived by principal components regression (PCR) are compared to results obtained from well-accepted standard methods. Good correlations are achieved for OH and COOH numbers and weaker, but still useful, correlations are also achieved for water content. Thus PCR of near-infrared spectra offers the potential to replace other methods of investigation that are time-consuming and expensive.
© (1992) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Sabine Haagen, Sabine Haagen, Detlef Drosdziok, Detlef Drosdziok, Gerd Reimann, Gerd Reimann, Klaus Wueller, Klaus Wueller, Joachim Oelichmann, Joachim Oelichmann, } "Determination of polymer end and functional groups by NIR spectrometry", Proc. SPIE 1575, 8th Intl Conf on Fourier Transform Spectroscopy, (1 March 1992); doi: 10.1117/12.56407; https://doi.org/10.1117/12.56407
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