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1 April 1992 Solution photochemistry of OCIO: excited-state dissociation and isomerization
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Abstract
The photodissociation dynamics of OClO in room temperature water solution were investigated using picosecond transient absorption spectroscopy. The time dependent data are consistent with the conclusion that following excitation at 355 nm, 90% of the OCIO molecules photodissociate forming ClO and 0 and 10% isomerize forming CIOO. The photochemically generated CIOO thermally decomposes into Cl and 02 with a rate constant of -6.7 x 1O9 s-1.
© (1992) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Robert C. Dunn, Bret N. Flanders, and John Douglas Simon "Solution photochemistry of OCIO: excited-state dissociation and isomerization", Proc. SPIE 1638, Optical Methods for Time- and State-Resolved Chemistry, (1 April 1992); https://doi.org/10.1117/12.58125
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