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24 June 1993 Degradation of vacuum-exposed SiO2 laser windows
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Abstract
Observations of a damage phenomenon at the surface of fused silica and crystalline quartz windows are presented. Uncoated windows were mounted at Brewster's angle to facilitate the introduction of a vacuum chamber directly into the cavity of an Ar-ion laser (488 - 514 nm). The transmission of these windows, prior to evacuating the chamber to less than 1 Torr, approaches the theoretical value of > 99.9%, remaining constant indefinitely. However in our normal usage, the chamber is evacuated (P < 10-7 Torr), exposing the windows to high vacuum as well as UV borelight from the laser discharge. After several hours of operation, the intracavity power is observed to decrease monotonically (by approximately 15% per hour) accompanied by the development of a red fluorescence on the inside window surface where exposed to the visible laser radiation. Partial rejuvenation of the windows can be accomplished by reintroduction of gas into the vacuum chamber. Possible damage mechanisms are presented.
© (1993) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Thomas M. Stephan, B. Van Zyl, and Robert C. Amme "Degradation of vacuum-exposed SiO2 laser windows", Proc. SPIE 1848, 24th Annual Boulder Damage Symposium Proceedings -- Laser-Induced Damage in Optical Materials: 1992, (24 June 1993); https://doi.org/10.1117/12.147442
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