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Optical absorption spectra for size-selected Hg;t" and Hg;t+ clusters show an abrupt transition to a collective, plasmon-like absorption as a function of increasing cluster size. The position of the one plasmon peak as well as the width of the plasmon peak is studied in detail. A temperature dependance is conjectured for the width. A strong influence of electronic correlations on the cluster size dependence of the oscillator strength is observed.
H. Haberland,Bernd von Issendorf,Yufing Ji, andThomas Kolar
"Optical spectra of size-selected mercury cluster ions", Proc. SPIE 1858, Laser Techniques for State-Selected and State-to-State Chemistry, (22 April 1993); https://doi.org/10.1117/12.143234
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H. Haberland, Bernd von Issendorf, Yufing Ji, Thomas Kolar, "Optical spectra of size-selected mercury cluster ions," Proc. SPIE 1858, Laser Techniques for State-Selected and State-to-State Chemistry, (22 April 1993); https://doi.org/10.1117/12.143234