Resonance flourescence examination of the allyl radical B[12A1] and C[22B1] excited states

James D. Getty; Xianming Liu; Peter B. Kelly

doi:10.1117/12.143104

22 April 1993 Resonance flourescence examination of the allyl radical B[12A1] and C[22B1] excited states

James D. Getty, Xianming Liu, Peter B. Kelly

Proceedings Volume 1858, Laser Techniques for State-Selected and State-to-State Chemistry; (1993) https://doi.org/10.1117/12.143104
Event: OE/LASE'93: Optics, Electro-Optics, and Laser Applications in Scienceand Engineering, 1993, Los Angeles, CA, United States

Abstract

The B[1²A₁] and C[2²B₁] electronic states of the allyl radical have been examined by laser spectroscopy. The spectra are classified according to the theory of resonance secondary radiation as predominantly resonance fluorescence in the excitation wavelength range from 242 nm to 250 nm. The observed emission spectra are indicative of the vibronic nature of the absorption bands. The excited state vibrational frequencies for (nu) ₇ and (nu) ₁₂ of the C[2²B₁] state are found to be 375 cm^-1 and 509 cm^-1.

Citation Download Citation

James D. Getty, Xianming Liu, and Peter B. Kelly "Resonance flourescence examination of the allyl radical B[12A1] and C[22B1] excited states", Proc. SPIE 1858, Laser Techniques for State-Selected and State-to-State Chemistry, (22 April 1993); https://doi.org/10.1117/12.143104

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available