22 April 1993 Resonance flourescence examination of the allyl radical B[12A1] and C[22B1] excited states
Author Affiliations +
Proceedings Volume 1858, Laser Techniques for State-Selected and State-to-State Chemistry; (1993) https://doi.org/10.1117/12.143104
Event: OE/LASE'93: Optics, Electro-Optics, and Laser Applications in Scienceand Engineering, 1993, Los Angeles, CA, United States
Abstract
The B[12A1] and C[22B1] electronic states of the allyl radical have been examined by laser spectroscopy. The spectra are classified according to the theory of resonance secondary radiation as predominantly resonance fluorescence in the excitation wavelength range from 242 nm to 250 nm. The observed emission spectra are indicative of the vibronic nature of the absorption bands. The excited state vibrational frequencies for (nu) 7 and (nu) 12 of the C[22B1] state are found to be 375 cm-1 and 509 cm-1.
© (1993) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
James D. Getty, Xianming Liu, and Peter B. Kelly "Resonance flourescence examination of the allyl radical B[12A1] and C[22B1] excited states", Proc. SPIE 1858, Laser Techniques for State-Selected and State-to-State Chemistry, (22 April 1993); doi: 10.1117/12.143104; https://doi.org/10.1117/12.143104
PROCEEDINGS
10 PAGES


SHARE
Advertisement
Advertisement
RELATED CONTENT


Back to Top