14 May 1993 Ion exchange for optical waveguides in ZnSe crystals: regularities and specific features
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Proceedings Volume 1932, Guided-Wave Optics; (1993) https://doi.org/10.1117/12.145579
Event: Guided Wave Optics, 1992, Moscow, Russian Federation
Abstract
A new method has been applied to form CduZn1-uSe waveguides -- ion exchange in the melts of salts. The regularities and specific features of ion exchange processes Cd2+ yields Zn2+ in ZnSe powder and single crystal plates have been studied. CduZn1-uSe solid solution obeys the model of regular solution. Temperature dependencies of equilibrium constant and interaction energy of strained and unstrained CduZn1-uSe solid solutions have been defined. We proposed the model taking into account the role of lattice misfit-induced stresses and dislocations in the ion exchange equilibrium. The depth profiles of elements and the refractive-index profiles in the ion exchanged Cd:ZnSE waveguides were analyzed and temperature dependencies of the self-diffusion coefficients of Cd2+ and Zn2+ ions were determined.
© (1993) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Vyacheslav A. Fedorov, Vyacheslav A. Fedorov, V. A. Ganshin, V. A. Ganshin, Yuri N. Korkishko, Yuri N. Korkishko, } "Ion exchange for optical waveguides in ZnSe crystals: regularities and specific features", Proc. SPIE 1932, Guided-Wave Optics, (14 May 1993); doi: 10.1117/12.145579; https://doi.org/10.1117/12.145579
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