Silicon-based donor-acceptor compounds: synthesis and nonlinear optical characterization

Diny Hissink; Henk J. Bolink; Jan-Willem Eshuis; Paul F. van Hutten; George G. Malliaras; Georges Hadziioannou

doi:10.1117/12.165285

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16 December 1993 Silicon-based donor-acceptor compounds: synthesis and nonlinear optical characterization

Diny Hissink, Henk J. Bolink, Jan-Willem Eshuis, Paul F. van Hutten, George G. Malliaras, Georges Hadziioannou

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Proceedings Volume 2025, Nonlinear Optical Properties of Organic Materials VI; (1993) https://doi.org/10.1117/12.165285
Event: SPIE's 1993 International Symposium on Optics, Imaging, and Instrumentation, 1993, San Diego, CA, United States

Abstract

We have synthesized silicon-based donor-acceptor compounds that are transparent in the visible and have moderate values of the first hyperpolarizability, (beta) , which are measured with Hyper-Rayleigh Scattering (HRS). The spectroscopic properties (UV-VIS) are studied by investigating the influence of the donor and acceptor strength and the chain length on the absorption maxima and (lambda) _cutoff values. We will focus the perfluorobutylsulfonyl in studies concerning functionalization and incorporation into a polymer matrix.

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Diny Hissink, Henk J. Bolink, Jan-Willem Eshuis, Paul F. van Hutten, George G. Malliaras, and Georges Hadziioannou "Silicon-based donor-acceptor compounds: synthesis and nonlinear optical characterization", Proc. SPIE 2025, Nonlinear Optical Properties of Organic Materials VI, (16 December 1993); https://doi.org/10.1117/12.165285

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