31 January 1994 Fourier transform infrared study of the Van der Waals molecules between alkyl chlorides and hydrogen chloride in liquified argon
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Proceedings Volume 2089, 9th International Conference on Fourier Transform Spectroscopy; (1994) https://doi.org/10.1117/12.166581
Event: Fourier Transform Spectroscopy: Ninth International Conference, 1993, Calgary, Canada
Abstract
Mid-IR spectra (4000 - 400 cm-1) of mixtures of HCl with methyl-d3, ethyl- d5, n-propyl, isopropyl-d7 or t-butyl chloride, dissolved in liquified argon (95 - 117 K) and liquified krypton (122 - 148 K) have been investigated. In all cases the formation of a 1:1 Van der Waals molecule between HCl and the alkyl chloride was observed. At higher concentrations, a new absorption band, due to a 1:2 complex (RCl)(DOT)(HCl)2 was found. Ab initio structural calculations at the RHF/6-31G** level show the complexes have an approximate L-shape.
© (1994) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Benjamin J. van der Veken, Benjamin J. van der Veken, Wouter Herrebout, Wouter Herrebout, } "Fourier transform infrared study of the Van der Waals molecules between alkyl chlorides and hydrogen chloride in liquified argon", Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); doi: 10.1117/12.166581; https://doi.org/10.1117/12.166581
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