Hydrogen bonding in crystalline sugars: a variable-temperature FTIR study on methyl beta-D-galactopyranoside

Bert Lutz; Marjan Olthof; Hendrik J. Luinge; John H. van der Maas

doi:10.1117/12.166635

31 January 1994 Hydrogen bonding in crystalline sugars: a variable-temperature FTIR study on methyl β-D-galactopyranoside

Bert Lutz, Marjan Olthof, Hendrik J. Luinge, John H. van der Maas

Author Affiliations +

Proceedings Volume 2089, 9th International Conference on Fourier Transform Spectroscopy; (1994) https://doi.org/10.1117/12.166635
Event: Fourier Transform Spectroscopy: Ninth International Conference, 1993, Calgary, Canada

Abstract

Low temperature measurements have been successfully applied to study the H-bond network in methyl-(beta) -D-galactopyranoside in the crystalline phase. Deuterium exchange experiments were required to get insight into vibrational coupling of the OH groups in the chain. Wavenumber-temperature coefficients may be used to characterize the O- H(DOT)(DOT)(DOT)O bonds. The effect of deuterium exchange on H-bond cooperativity is recognized in the OH stretching absorption at approximately 3360 cm^-1 and the corresponding OD.

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Bert Lutz, Marjan Olthof, Hendrik J. Luinge, and John H. van der Maas "Hydrogen bonding in crystalline sugars: a variable-temperature FTIR study on methyl β-D-galactopyranoside", Proc. SPIE 2089, 9th International Conference on Fourier Transform Spectroscopy, (31 January 1994); https://doi.org/10.1117/12.166635

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