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17 June 1994 Photochemistry of the N2O-H2O complexes produced in supersonic jets
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Abstract
We have studied 193 nm photodissociation of N2O(DOT)H2O complexes produced in a supersonic jet resulting in the reactant-pair reaction N2O(DOT)H2O + hv yields 2OH + N2. Measured internal energy, and spin-orbit and (Lambda) -doublet distributions in OH by laser induced fluorescence suggest a reaction scheme much different from the corresponding bimolecular reaction, O(1D) + H2O yields 2OH, observed in bulb experiments. The reaction should occur indirectly with early escape of N2 and proceed slowly in a relatively long-lived intermediate O(DOT)H2O.
© (1994) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Ichiro Hanazaki, Hong-Lae Kim, and Masao Takayanagi "Photochemistry of the N2O-H2O complexes produced in supersonic jets", Proc. SPIE 2124, Laser Techniques for State-Selected and State-to-State Chemistry II, (17 June 1994); https://doi.org/10.1117/12.178110
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