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16 October 1995LiYF4 (YLF) single crystals doped with rare-earth elements
E. Kowalczyk,1 Z. Kowalczyk,2 K. Grasza,3 M. Gala,4 Tadeusz Lukasiewicz4
1Institute of Vacuum Technology (Poland) 2Warsaw Univ. of Technology (Poland) 3Institute of Physics (Poland) 4Institute of Electronic Materials Technology (Poland)
LiYF4 (YLF) is a very promising host material for lasers. Investigation of the spectroscopic and physical properties of YLF:Nd has suggested that this material may be a better candidate than Nd:YAG for generating short pulses with high peak power. This is a distinct advantage for many applications. Stimulated emission is attained at 1053 nm and 1047 nm. Also upconservation laser action in YLF and YLF:Er crystals is reported. More recently YLF doped with rare-earth elements has gained some attention. Pulsed room-temperature laser action at 2.06 micrometer has been achieved using YLF:Ho sensitized with Er and Tm. Using YLF:Pr blue light emission at 479 nm at room temperature was observed. Growth experiments of YLF:Nd crystals were carried by the Bridgman method. A vacuum furnace with cylindrical molybdenum heater and graphite crucible have been used. The temperature gradient of 25 degrees Celsius/cm has been achieved by using a stainless steel liner in the lower part of the furnace. The growth was performed in a nitrogen atmosphere. First crystals of YLF:Nd have been obtained.
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E. Kowalczyk, Z. Kowalczyk, K. Grasza, M. Gala, Tadeusz Lukasiewicz, "LiYF4 (YLF) single crystals doped with rare-earth elements," Proc. SPIE 2373, Solid State Crystals: Materials Science and Applications, (16 October 1995); https://doi.org/10.1117/12.224989