8 December 1995 Excited-state dynamics of C60 and η2-C60Pd(PPh3)2
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Abstract
Transient absorption and pump-probe experiments have been performed on degassed toluene solutions of C60 and eta2-C60Pd(PPh3)2. Previous reports of a 1.2 ns singlet state lifetime for C60 have been confirmed. For the eta2-C60Pd(PPh3)2 compound an extremely fast decay of 12 ps has been observed which is believed to be derived from the rapid depopulation of a charge transfer band which has formed due to electron transfer from metal to ligand.
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Jonathan D. Callaghan, N. T. H. White, Declan N. Weldon, G. S. Beddard, Werner J. Blau, "Excited-state dynamics of C60 and η2-C60Pd(PPh3)2", Proc. SPIE 2530, Fullerenes and Photonics II, (8 December 1995); doi: 10.1117/12.228114; https://doi.org/10.1117/12.228114
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KEYWORDS
Absorption

Metals

Beam splitters

Molecules

Picosecond phenomena

Chemistry

Fullerenes

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