18 September 1995 State-specific chemistry of atomic and ligated transition metal ions
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The ability of iron ions to activate methane is studied in detail by using a guided ion beam tandem mass spectrometer. State-specific results for ground state Fe+(6D) and first excited state Fe+(4F) with methane are determined by varying the source conditions for Fe+. A more complete picture of the potential energy surface for this reaction is obtained by examining one of the reverse processes, FeCH2+ plus H2. The influence of ligands on the metal reactivity is also investigated for this reaction system. The reactions of methane with both FeCO+ and Fe(H2O)+ are examined with the latter exhibiting much greater reactivity. This result is attributed to the more favorable thermodynamics associated with the electronic configuration on Fe+ as induced by the H2O ligand.
© (1995) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Peter B. Armentrout, Peter B. Armentrout, Christy L. Haynes, Christy L. Haynes, Brenda L. Tjelta, Brenda L. Tjelta, Yumin Chen, Yumin Chen, "State-specific chemistry of atomic and ligated transition metal ions", Proc. SPIE 2548, Laser Techniques for State-Selected and State-to-State Chemistry III, (18 September 1995); doi: 10.1117/12.220855; https://doi.org/10.1117/12.220855

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