Analysis of contributions of different polarization interactions to the shifts of polar molecule absorption lines

Valentina N. Stroinova

doi:10.1117/12.267782

3 March 1997 Analysis of contributions of different polarization interactions to the shifts of polar molecule absorption lines

Valentina N. Stroinova

Author Affiliations +

Proceedings Volume 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy; (1997) https://doi.org/10.1117/12.267782
Event: 12th Symposium and School on High Resolution Molecular Spectroscopy, 1996, St. Petersburg, Russian Federation

Abstract

The computational estimations of the contributions of polarization interactions into the shifts were made. Such analysis allows one to define the value of contributions from the first and second orders of perturbation theory into the shifts and to solve the inverse problem for hyper- polarizability. Analysis for the shifts of H₂O, S₂O, NO₂, NO, H₂S, O₃, CO polar molecule absorption lines induced by Ar pressure were carried out. Estimation results shows the contribution of high order polarization interaction can reach 35%.

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Valentina N. Stroinova "Analysis of contributions of different polarization interactions to the shifts of polar molecule absorption lines", Proc. SPIE 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy, (3 March 1997); https://doi.org/10.1117/12.267782

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