3 March 1997 Magnetic predissociation in Te2 B 1u
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Proceedings Volume 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy; (1997) https://doi.org/10.1117/12.267763
Event: 12th Symposium and School on High Resolution Molecular Spectroscopy, 1996, St. Petersburg, Russian Federation
Abstract
We report a registration of magnetic predissociation (MPD) of electronically excited molecules via peculiarities in magnetic field B induced alignment-orientation conversion (AOC). Non-linear magnetic energy shift and heterogeneous MPD produce dispersion type fluorescence circularity signals C(B) of different sign. Measurements on B 1u-, v(J) equals 2(96) state of 130Te2 yielded natural Cvhet equals plus or minus 6 s-1/2 and magnetic (alpha) vhet equals minus or plus 9 multiplied by 103 s-1/2T-1 rate constants of heterogeneous PD, supposing that the B1u- state PD takes place through Ou- state continuum.
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Marcis P. Auzinsh, A. V. Stolyarov, M. Tamanis, R. S. Ferber, "Magnetic predissociation in Te2 B 1u", Proc. SPIE 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy, (3 March 1997); doi: 10.1117/12.267763; https://doi.org/10.1117/12.267763
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