Magnetic predissociation in Te2 B 1u

Marcis P. Auzinsh; A. V. Stolyarov; M. Tamanis; R. S. Ferber

doi:10.1117/12.267763

3 March 1997 Magnetic predissociation in Te₂ B 1_u

Marcis P. Auzinsh, A. V. Stolyarov, M. Tamanis, R. S. Ferber

Proceedings Volume 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy; (1997) https://doi.org/10.1117/12.267763
Event: 12th Symposium and School on High Resolution Molecular Spectroscopy, 1996, St. Petersburg, Russian Federation

Abstract

We report a registration of magnetic predissociation (MPD) of electronically excited molecules via peculiarities in magnetic field B induced alignment-orientation conversion (AOC). Non-linear magnetic energy shift and heterogeneous MPD produce dispersion type fluorescence circularity signals C(B) of different sign. Measurements on B 1_u^-, v(J) equals 2(96) state of ¹³⁰Te₂ yielded natural C_v^het equals plus or minus 6 s^-1/2 and magnetic (alpha) _v^het equals minus or plus 9 multiplied by 10³ s^-1/2T^-1 rate constants of heterogeneous PD, supposing that the B1_u^- state PD takes place through O_u^- state continuum.

Citation Download Citation

Marcis P. Auzinsh, A. V. Stolyarov, M. Tamanis, and R. S. Ferber "Magnetic predissociation in Te₂ B 1_u", Proc. SPIE 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy, (3 March 1997); https://doi.org/10.1117/12.267763

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