3 March 1997 Orientational relaxation of spherical top molecules in gases and liquids: effect of collision intensity
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Proceedings Volume 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy; (1997) https://doi.org/10.1117/12.267784
Event: 12th Symposium and School on High Resolution Molecular Spectroscopy, 1996, St. Petersburg, Russian Federation
Abstract
In order to study the influence of correlation of the angular momenta before and after collision on the course of orientational relaxation of spherical top molecules, a Markovian master equation with the collision kernel by Keilson and Storer is considered. The equation is solved analytically in the case of the complete angular momentum reorientation due to a collision. The results obtained allow one to establish the upper and the lower limit of the time development of the orientational correlation functions.
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A. P. Blokhin, M. F. Gelin, "Orientational relaxation of spherical top molecules in gases and liquids: effect of collision intensity", Proc. SPIE 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy, (3 March 1997); doi: 10.1117/12.267784; https://doi.org/10.1117/12.267784
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