Vector correlations in photodissociation of polyatomic molecules

A. P. Blokhin; M. F. Gelin; S. A. Polubisok

doi:10.1117/12.267743

3 March 1997 Vector correlations in photodissociation of polyatomic molecules

A. P. Blokhin, M. F. Gelin, S. A. Polubisok

Proceedings Volume 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy; (1997) https://doi.org/10.1117/12.267743
Event: 12th Symposium and School on High Resolution Molecular Spectroscopy, 1996, St. Petersburg, Russian Federation

Abstract

To describe contribution of the parent molecule rotation and the interfragment repulsive forces into the rotational excitation of molecular fragments produced through the photo-dissociation process, a simple model is proposed. The model is proved to be useful in estimating the magnitude of the additional angular momentum, that originates from the interfragment repulsive forces, by observation of the polarized fluorescence of photoproducts.

Citation Download Citation

A. P. Blokhin, M. F. Gelin, and S. A. Polubisok "Vector correlations in photodissociation of polyatomic molecules", Proc. SPIE 3090, 12th Symposium and School on High-Resolution Molecular Spectroscopy, (3 March 1997); https://doi.org/10.1117/12.267743

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