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9 October 1997 Bifunctional dimer and polymers for photorefractive applications
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Abstract
We present the electro-optic, photoconductive and photorefractive characterization of a novel organic photorefractive structure. It is composed of a bifunctional dimeric molecule combining both photoconduction and electro-optic properties. This low molecular weight material is a glass, showing a glass transition temperature (Tg) at 27 degrees C. Doped with (2,4,7-trinitro-9-fluorenylidene)malononitrile (TNFDM) as photosensitizer (1% wt), this dimer exhibits 200 cm-1 photorefractive gain at 633 urn for 50 V μm-1 electric field applied. Compared to usual doped polymers which generally show inhomogeneities in the mixtures, this material presents good optical quality thanks to its monophasic character. A serie of functionalized copolymer has also been synthesized, in which the ratio of the chromophore moieties over the charge carrier moieties was varied. These copolymers show photoconductivity but no photorefractivity.
© (1997) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Loic Mager and Stephane Mery "Bifunctional dimer and polymers for photorefractive applications", Proc. SPIE 3144, Xerographic Photoreceptors and Organic Photorefractive Materials II, (9 October 1997); https://doi.org/10.1117/12.290236
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