9 October 1997 New photorefractive polymers for real-time holography
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Abstract
We investigated polymeric materials based on polysiloxane (PSX), polymethylmethacrylate (PMMA), polyurethane (PU), as well as a triphenylamin-based glass (DRDCTA) with respect to their photorefractive properties. Electric-field dependencies of the two-beam coupling gain, diffraction efficiencies, refractive index amplitudes and holographic rise-times could be obtained by means of two-wave mixing and degenerate four-wave mixing measurements. The examined PSX polymer systems were composed of a photoconducting polysiloxane host doped with trinitrofluorenone (TNF) as a sensitizing moiety and various chromophores, namely, an azo derivative, a stilben derivative and a tolan derivative. Due to their comparatively low glass-transition temperatures Tg, an orientational enhancement of the photorefractive properties was observed. Furthermore, the influence of photoisomerisation (based on trans-cis-trans cycles) on the holographical properties could be determined for the different chromophores. In addition, a class of fully functionalized polymers with azo chromophores and carbazole-units covalently attached to PMMA- and PU-backbones was synthesized. These systems show comparatively high glass transition temperatures of more than 80 degrees C. The third type of materials investigated is a glass of triphenylamin with attached carbazole and NLO-chromophore moieties. It has a glass transition temperature of 120 degrees C. For the high-Tg materials, poling procedures--essential for the photorefractive properties--could be monitored in-situ by second-harmonic generation. Absolute values for the nonlinear Pockets coefficients χ(2) (-ω; ω, 0) have been obtained by electro-optical measurements.
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Stefan Schloter, Stefan Schloter, Uwe Hofmann, Uwe Hofmann, Rainer Hagen, Rainer Hagen, Christoph Hohle, Christoph Hohle, Kai Ewert, Kai Ewert, Peter Strohriegl, Peter Strohriegl, C.-D. Eisenbach, C.-D. Eisenbach, Hans-Werner Schmidt, Hans-Werner Schmidt, Dietrich Haarer, Dietrich Haarer, } "New photorefractive polymers for real-time holography", Proc. SPIE 3144, Xerographic Photoreceptors and Organic Photorefractive Materials II, (9 October 1997); doi: 10.1117/12.290234; https://doi.org/10.1117/12.290234
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