Spectroscopy and dynamics involving interacting electronic states

Hans-Peter Loock; Jianying Cao; Walter J. Balfour; Chi Zhou; Charles Qian

doi:10.1117/12.308386

15 May 1998 Spectroscopy and dynamics involving interacting electronic states

Hans-Peter Loock, Jianying Cao, Walter J. Balfour, Chi Zhou, Charles Qian

Proceedings Volume 3271, Laser Techniques for State-Selected and State-to-State Chemistry IV; (1998) https://doi.org/10.1117/12.308386
Event: Optoelectronics and High-Power Lasers and Applications, 1998, San Jose, CA, United States

Abstract

The deperturbation analysis of ReN and nonadiabatic dissociation dynamics of BrCl and BrNO are reported. In the case of ReN, couplings between different electronic states changes apparent molecular properties such as rotational constants and excited state lifetimes. An experimental approach which enabled us to separated the contributions to the mixed states from specified energies and the spin-orbit branching ratio was measured as a function of the excitation energy. The correlation of the spin-orbit states of the photofragments was established. Such observations enabled us to establish nonadiabatic dissociation mechanisms. In both the spectroscopy and dissociation dynamics studies, the coupling between the nuclear and electronic degrees of freedom was investigated.

Citation Download Citation

Hans-Peter Loock, Jianying Cao, Walter J. Balfour, Chi Zhou, and Charles Qian "Spectroscopy and dynamics involving interacting electronic states", Proc. SPIE 3271, Laser Techniques for State-Selected and State-to-State Chemistry IV, (15 May 1998); https://doi.org/10.1117/12.308386

ACCESS THE FULL ARTICLE

INSTITUTIONAL
Select your institution to access the SPIE Digital Library.

SELECT YOUR INSTITUTION

PERSONAL
Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.

PERSONAL SIGN IN

No SPIE Account? Create one

PURCHASE THIS CONTENT

SUBSCRIBE TO DIGITAL LIBRARY

50 downloads per 1-year subscription

Members: $195

Non-members: $335 ADD TO CART

25 downloads per 1 - year subscription

Members: $145

Non-members: $250 ADD TO CART

PURCHASE SINGLE ARTICLE

Includes PDF, HTML & Video, when available