17 April 1998 Orientation-induced molecular rectification in polymer films: improving the efficiency of polymer photovoltaic cells
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Abstract
In an attempt to build single polymer film photovoltaic cells, we underline the intrinsic rectifying nature of an oriented polymeric material. Orientation of the initially symmetric structure is performed through DC-field ordering of the polar molecules contained in the polymer. The internal field induced in the polymeric material is evidenced by the induction of a rectifying current-voltage characteristic. Second harmonic generation is used as a probe of the molecular order. Orientation induced rectification is proportional to the molecular order. This preparation technique opens a new route for the improvement of organic-semiconductor devices efficiency.
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Jean-Michel Nunzi, Jean-Michel Nunzi, Lionel Sicot, Lionel Sicot, Carole Sentein, Carole Sentein, Celine Fiorini-Debuisschert, Celine Fiorini-Debuisschert, } "Orientation-induced molecular rectification in polymer films: improving the efficiency of polymer photovoltaic cells", Proc. SPIE 3281, Polymer Photonic Devices, (17 April 1998); doi: 10.1117/12.305414; https://doi.org/10.1117/12.305414
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