Photochemical behavior in dichromated gelatin

Michel Bolte; Christine Pizzocaro

doi:10.1117/12.301417

1 January 1998 Photochemical behavior in dichromated gelatin

Michel Bolte, Christine Pizzocaro

Author Affiliations +

Proceedings Volume 3347, Optical Information Science and Technology (OIST97): Optical Recording Mechanisms and Media; (1998) https://doi.org/10.1117/12.301417
Event: Optical Information Science and Technology, 1997, Moscow, Russian Federation

Abstract

The photochemical behavior of dichromated gelatin and of different aminoacids-chromium (VI) systems was investigated. The photoredox process that takes place between chromium (VI) (complexed or not) and the organic moiety leads to the formation of chromium (V) which is then reduced to chromium (III) likely complexed to the medium. In chromium (VI)- aminoacids systems, the quantum yield (Phi) , that measures the efficiency of a photon at a given wavelength, strongly depends on the reductive properties of the aminoacid. (Phi) is proportional to aminoacid concentration. In irradiated DCG films, the formation of chromium (V) is observed and this intermediate species appears to be surprisingly stable in the polymeric matrix.

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Michel Bolte and Christine Pizzocaro "Photochemical behavior in dichromated gelatin", Proc. SPIE 3347, Optical Information Science and Technology (OIST97): Optical Recording Mechanisms and Media, (1 January 1998); https://doi.org/10.1117/12.301417

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