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The influence of the fluorine-containing precursor type in the MCVD process on the size of soot particles is investigated by the method of laser ultramicroscope. The results of these measurements have shown that Freon-113 decreases the content of large soot particles, while SiF4 does not. These results suggest an explanation of the optical loss reduction in highly GeO2- or P2O5- doped single-mode fibers due to co-doping of the fiber core with fluorine.
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Mikhail M. Bubnov, Eugeni M. Dianov, Olga N. Egorova, Sergey L. Semjonov, Alexei N. Guryanov, L. A. Ketkova, Vladimir F. Khopin, "Influence of fluorine codoping on optical losses in Ge- and P-doped fibers," Proc. SPIE 4216, Optical Devices for Fiber Communication II, (2 February 2001); https://doi.org/10.1117/12.414112