Metallophthalocyanines synthesized for different metals such as Ni, Cr, Ag, Mg, Cu, Cd, Al, etc by chemical methods were characterized with FTIR, TGA etc. Sensing of humidity and different gases such as NOx, H2, O2, CO2. N2, ammonia, alcohol vapours etc were checked with 2-probe technique with monitoring change in resistance change. These samples have excellent stability against heat, light, air, and hence it has considerable attention for environmentally stable gas sensor. The electrical property of these samples were investigated at room teniperature and at normal atmospheric pressure from low to 98% relative Humidity. It was observed that these samples shows good response and recovery for humidity sensing.