19 October 2001 Optical power limiting of [M(DMID)2 ][C]x and [M(DMIT)2][C]X(M=NI,CU)(C=TMA;TBA)
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Proceedings Volume 4580, Optoelectronics, Materials, and Devices for Communications; (2001) https://doi.org/10.1117/12.445011
Event: Asia-Pacific Optical and Wireless Communications Conference and Exhibit, 2001, Beijing, China
Abstract
Optical limiting property of two types of charge transfer salt [M(DMID)2][C]x and [M(DMIT)2][C]x (M = Ni, Cu) (C=TMA, TBA) is studied. The comparison of these two series complexes demonstrates that the optical limiting effect of the Ni-based complexes is better than that of the Cu-based complexes, both of them are a little less than that of C60. The nonlinear absorption coefficient that determined by optical limiting technique for Ni-based complexes is about one order of magnitude higher than that of Cu-based complexes. On the other hand, partial charge transfer may enhance the optical limiting effect in the Cu-based complexes, but it doesn't occur in the Ni-based complexes. All may be attributed to the typical column structure that caused by plan configuration.
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Shuang Zhang, Shuang Zhang, Peiji Wu, Peiji Wu, Peng Wang, Peng Wang, Cheng Ye, Cheng Ye, } "Optical power limiting of [M(DMID)2 ][C]x and [M(DMIT)2][C]X(M=NI,CU)(C=TMA;TBA)", Proc. SPIE 4580, Optoelectronics, Materials, and Devices for Communications, (19 October 2001); doi: 10.1117/12.445011; https://doi.org/10.1117/12.445011
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