Vibrational spectra and the structure peculiarity of TiO2 different polycrystalline forms

V. V. Shimanovskaya; T. A. Khalyavka; Galina A. Puchkovska; T. V. Bezrodna; V. V. Strelko; T. S. Veblaya; J. Baran; H. Ratajczak

doi:10.1117/12.486638

11 December 2002 Vibrational spectra and the structure peculiarity of TiO₂ different polycrystalline forms

V. V. Shimanovskaya, T. A. Khalyavka, Galina A. Puchkovska, T. V. Bezrodna, V. V. Strelko, T. S. Veblaya, J. Baran, H. Ratajczak

Author Affiliations +

Proceedings Volume 4938, Selected Papers from the International Conference on Spectroscopy of Molecules and Crystals; (2002) https://doi.org/10.1117/12.486638
Event: XV International School on Spectroscopy of Molecules and Crystals, 2001, Chernivsti, Ukraine

Abstract

Particularly pure samples of titanium dioxide with a different crystalline structure and a different construction of TiO₂ polycrystaline particles which were produced by thermal hydrolysis of TiCl₄ hydrochloric acid solutions, were studied by methods of IR and Raman spectroscopy. The assignment of IR and Raman spectral bands to vibrations of different symmetry types has been performed. In accordance with positions and half-width of Raman lattice vibrational band 'ν=143 cm^-1'. The stoichiometric composition estimation of TiO₂ different crystalline phases has been carried out according to data obtained about the position and half-width of the lattice Raman vibrational band. The intensity and frequency of IR bands in the region of 1250-900 cm^-1 were shown to be sensitive to a type of TiO₂ crystalline composition and to the physically adsorbed water content.

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V. V. Shimanovskaya, T. A. Khalyavka, Galina A. Puchkovska, T. V. Bezrodna, V. V. Strelko, T. S. Veblaya, J. Baran, and H. Ratajczak "Vibrational spectra and the structure peculiarity of TiO₂ different polycrystalline forms", Proc. SPIE 4938, Selected Papers from the International Conference on Spectroscopy of Molecules and Crystals, (11 December 2002); https://doi.org/10.1117/12.486638

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